Synthesis and recognition behavior of multi-point receptors with binding sites for different metal ions

被引:16
作者
Saiki, T [1 ]
Iwabuchi, J [1 ]
Akine, S [1 ]
Nabeshima, T [1 ]
机构
[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan
关键词
calixarene; Ag complex; cooperative complexation; ternary complex; ion recognition;
D O I
10.1016/j.tetlet.2004.07.140
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Novel multi-point receptors which have a calix[4]arene skeleton, two esters, and two bipyridine moieties with a polyether chain were designed and synthesized. The host with shorter polyethers recognizes Na+ and Ag+ cooperatively, and the host with longer polyethers captures them independently. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7007 / 7010
页数:4
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