Phosphorus nanorods -: Two allotropic modifications of a long-known element

被引：101

作者：

Pfitzner, A ^{[1
]}

Bräu, MF

Zweck, J

Brunklaus, G

Eckert, H

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93040 Regensburg, Germany

[2] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany

[3] Univ Regensburg, Inst Expt & Angew Phys, D-93040 Regensburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 32期

关键词：

element modification; nanorods; NMR spectroscopy; phosphorus;

D O I：

10.1002/anie.200460244

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Extracting the P: Two novel amorphous allotropes of elemental phosphorus that consist of polymeric chains (see example depicted) were obtained in a pure form by extraction from their copper iodide adducts with an aqueous solution of potassium cyanide. 31P NMR spectra and high-resolution TEM images suggest that the structure of these phosphorus nanorods is unchanged after extraction.

引用

页码：4228 / 4231

页数：4

共 17 条

[1] COVALENT STRUCTURES OF PHOSPHORUS - A COMPREHENSIVE THEORETICAL-STUDY [J].

BOCKER, S ;

HASER, M .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (02) :258-286

[2] NMR studies of phosphorus chalcogenide-copper iodide coordination compounds [J].

Brunklaus, G ;

Chan, JCC ;

Eckert, H ;

Reiser, S ;

Nilges, T ;

Pfitzner, A .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (17) :3768-3776

[3]

Corbridge D. E D.E.C, 2000, PHOSPHORUS 2000

[4] Electrical properties of Cu2P3I2 [J].

Freudenthaler, E ;

Pfitzner, A ;

Sinclair, DC .

MATERIALS RESEARCH BULLETIN, 1996, 31 (02) :171-176

[5] The atomic distribution in red and black phosphorus and the crystal structure of black phosphorus [J].

Hultgren, R ;

Gingrich, NS ;

Warren, BE .

JOURNAL OF CHEMICAL PHYSICS, 1935, 3 (06) :351-355

[6] PREPARATION, PROPERTIES, AND CRYSTAL-STRUCTURE OF THE SOLID ELECTROLYTES CU2P3I2 AND AG2P3I2 [J].

MOLLER, MH ;

JEITSCHKO, W .

JOURNAL OF SOLID STATE CHEMISTRY, 1986, 65 (02) :178-189

[7]

NILGES S, 2004, J MOL STRUC

[8]

Pfitzner A, 2000, CHEM-EUR J, V6, P1891, DOI 10.1002/1521-3765(20000602)6:11<1891::AID-CHEM1891>3.3.CO

[9]

2-O

[10] (CuI)(2)P-14: A novel phosphorus polymer in a copper halide matrix [J].

Pfitzner, A ;

Freudenthaler, E .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (02) :199-202

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