Synthesis and X-ray crystal structure of N,N′,N"-tris(2-thienylmethyl)-cis-1,3,5-triaminocyclohexane copper(II) dichloride

被引：4

作者：

Ye, N

Rogers, RD

Brechbiel, MW

Planalp, RP ^{[1
]}

机构：

[1] Univ New Hampshire, Dept Chem, Durham, NH 03824 USA

[2] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

[3] NIH, Chem Sect, Radiat Oncol Branch, Bethesda, MD 20892 USA

来源：

POLYHEDRON | 1998年 / 17卷 / 04期

关键词：

copper complexes; square-pyramidal; nitrogen donor ligands;

D O I：

10.1016/S0277-5387(97)00170-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex was synthesized by reaction of N,N',N''-tris(2-thienylmethyl)-cis-1,3,5-triaminocyclohexane (tachthioph) with copper(II) chloride in acetonitrile or methanol. Crystallographic characterization of Cu(tachthioph)Cl-2.MeCN reveals a typical Jahn-Teller-distorted square-pyramidal CuN3Cl2 coordination sphere. There is no interaction with the 2-methylenethiophene pendant arms. (C) 1998 Elsevier Science Ltd. All rights reserved.

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收藏

页码：603 / 606

页数：4

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