Formation of one-dimensional metal-water chain containing cyclic water hexamers

被引：161

作者：

Ye, BH ^{[1
]}

Ding, BB ^{[1
]}

Weng, YQ ^{[1
]}

Chen, XM ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 22期

关键词：

D O I：

10.1021/ic049232f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclic water hexamers containing 1-D metal-water chains have been observed in the complexes of [M(H(2)biiM)(2)(OH2)(2)](ina)(2)(.)4H(2)O [M = Zn (1) and Co (2), H(2)biim = 2,2'-biimidazole, ina = isoniconate]. The water clusters are trapped by the cooperative association of coordination interactions as well as hydrogen bonds.

引用

页码：6866 / 6868

页数：3

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