Novel transparent nanocomposite films based on chitosan and bacterial cellulose

被引:170
作者
Fernandes, Susana C. M. [1 ,2 ,3 ]
Oliveira, Lucia [1 ,2 ]
Freire, Carmen S. R. [1 ,2 ]
Silvestre, Armando J. D. [1 ,2 ]
Pascoal Neto, Carlos [1 ,2 ]
Gandini, Alessandro [1 ,2 ]
Desbrieres, Jacques [3 ]
机构
[1] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal
[2] Univ Aveiro, CICECO, P-3810193 Aveiro, Portugal
[3] Univ Pau & Adour Countries UPPA, IPREM, UMR 5254, CNRS, F-64053 Pau 09, France
关键词
POLYMER BLENDS; MEMBRANE; PERMEABILITY; ENHANCEMENT; COMPOSITES; NANOFIBERS; STRENGTH; BEHAVIOR;
D O I
10.1039/b919112g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New nanocomposite films based on different chitosan matrices (two chitosans with different DPs and one water soluble derivative) and bacterial cellulose were prepared by a fully green procedure by casting a water based suspension of chitosan and bacterial cellulose nanofibrils. The films were characterized by several techniques, namely SEM, AFM, X-ray diffraction, TGA, tensile assays and visible spectroscopy. They were highly transparent, flexible and displayed better mechanical properties than the corresponding unfilled chitosan films. These new renewable nanocomposite materials also presented reasonable thermal stability and low O-2 permeability.
引用
收藏
页码:2023 / 2029
页数:7
相关论文
共 42 条
[1]   PERMEABILITY AND BLOOD COMPATIBILITY PROPERTIES OF CHITOSAN-POLY(ETHYLENE OXIDE) BLEND MEMBRANES FOR HEMODIALYSIS [J].
AMIJI, MM .
BIOMATERIALS, 1995, 16 (08) :593-599
[2]  
Chen RH, 1996, CARBOHYD POLYM, V29, P353
[3]  
Ciechanska D, 2004, FIBRES TEXT EAST EUR, V12, P69
[4]   Hydrophobic derivatives of chitosan: Characterization and rheological behaviour [J].
Desbrieres, J ;
Martinez, C ;
Rinaudo, M .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 1996, 19 (01) :21-28
[5]   Pervaporative separation of ethanol/water azeotrope using a novel chitosan-impregnated bacterial cellulose membrane and chitosan-poly(vinyl alcohol) blends [J].
Dubey, V ;
Pandey, LK ;
Saxena, C .
JOURNAL OF MEMBRANE SCIENCE, 2005, 251 (1-2) :131-136
[6]  
Fang L, 2000, J APPL POLYM SCI, V76, P1785, DOI 10.1002/(SICI)1097-4628(20000620)76:12<1785::AID-APP8>3.0.CO
[7]  
2-B
[8]   Transparent and High Gas Barrier Films of Cellulose Nanofibers Prepared by TEMPO-Mediated Oxidation [J].
Fukuzumi, Hayaka ;
Saito, Tsuguyuki ;
Wata, Tadahisa ;
Kumamoto, Yoshiaki ;
Isogai, Akira .
BIOMACROMOLECULES, 2009, 10 (01) :162-165
[9]  
Gandini A, 2008, MONOMERS, POLYMERS AND COMPOSITES FROM RENEWABLE RESOURCES, P1, DOI 10.1016/B978-0-08-045316-3.00001-6
[10]   CHARACTERIZATION OF CELLULOSE CHITOSAN BLEND FILMS [J].
HASEGAWA, M ;
ISOGAI, A ;
ONABE, F ;
USUDA, M ;
ATALLA, RH .
JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 45 (11) :1873-1879