Features of reaction between fluorine-containing glycidyl ethers and alcohols in basic medium

被引:13
作者
Bazhin, D. N. [1 ]
Gorbunova, T. I. [1 ]
Zapevalov, A. Ya. [1 ]
Kirichenko, V. E. [1 ]
Saloutin, V. I. [1 ]
机构
[1] Russian Acad Sci, Postovskii Inst Organ Synth, Ural Div, Ekaterinburg 620219, Russia
基金
俄罗斯基础研究基金会;
关键词
Trifluoromethyl; Oxirane; Phase Transfer Catalysis; Oxirane Ring; Glycidyl Ether;
D O I
10.1134/S1070428007050041
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of fluorine-containing glycidyl ethers with various alcohols (i-PrOH, MeOH, PhOH, 2,2,3,3-tetrafluoropropanol) in basic medium resulted in products of regioselective opening of the oxirane ring. In reaction of 2,2,3,3-tetrafluoropropyloxymethyloxirane with 2-propanol under conditions of phase-transfer catalysis the main product was the corresponding 1,2-diol (yield 42%).
引用
收藏
页码:656 / 659
页数:4
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