Efficient Polymer Solar Cells Based on the Copolymers of Benzodithiophene and Thienopyrroledione

被引:335
作者
Zhang, Yong [1 ]
Hau, Steven K. [1 ]
Yip, Hin-Lap [1 ]
Sun, Ying [1 ]
Acton, Orb [1 ]
Jen, Alex K-Y. [1 ]
机构
[1] Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA
基金
美国国家科学基金会;
关键词
BANDGAP;
D O I
10.1021/cm100417z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bulk heterojunction solar cells based on a novel low band gap polymer, PBDTTPD, were investigated. In the conventional device structures, a power conversion efficiency of 4.1% could be achieved from the thin film blend of PBDTTPD:PC71BM(1:2) with a current density of 9.8mAcm-2, Voc of 0.84 V, and FF of ∼ 50%. The high Voc (0.87 V) is the result of the lower HOMO level of the polymer. In addition, inverted devices with PBDTTPD: PC71BM (1:2) as active layer were also investigated. © 2010 American Chemical Society.
引用
收藏
页码:2696 / 2698
页数:3
相关论文
共 22 条
[1]  
Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO
[2]  
2-A
[3]   Development of Novel Conjugated Donor Polymers for High-Efficiency Bulk-Heterojunction Photovoltaic Devices [J].
Chen, Junwu ;
Cao, Yong .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1709-1718
[4]   Recent Progress in Polymer Solar Cells: Manipulation of Polymer: Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells [J].
Chen, Li-Min ;
Hong, Ziruo ;
Li, Gang ;
Yang, Yang .
ADVANCED MATERIALS, 2009, 21 (14-15) :1434-1449
[5]   Synthesis of Conjugated Polymers for Organic Solar Cell Applications [J].
Cheng, Yen-Ju ;
Yang, Sheng-Hsiung ;
Hsu, Chain-Shu .
CHEMICAL REVIEWS, 2009, 109 (11) :5868-5923
[6]   Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].
Dennler, Gilles ;
Scharber, Markus C. ;
Brabec, Christoph J. .
ADVANCED MATERIALS, 2009, 21 (13) :1323-1338
[7]   Interfacial modification to improve inverted polymer solar cells [J].
Hau, Steven K. ;
Yip, Hin-Lap ;
Acton, Orb ;
Baek, Nam Seob ;
Ma, Hong ;
Jen, Alex K. -Y. .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (42) :5113-5119
[8]   Bandgap and molecular energy level control. of conjugated polymer photovoltaic materials based on benzo[1,2-b: 4,5-b']dithiophene [J].
Hou, Jianhui ;
Park, Mi-Hyae ;
Zhang, Shaoqing ;
Yao, Yan ;
Chen, Li-Min ;
Li, Juo-Hao ;
Yang, Yang .
MACROMOLECULES, 2008, 41 (16) :6012-6018
[9]   Synthesis of a Low Band Gap Polymer and Its Application in Highly Efficient Polymer Solar Cells [J].
Hou, Jianhui ;
Chen, Hsiang-Yu ;
Zhang, Shaoqing ;
Chen, Ruby I. ;
Yang, Yang ;
Wu, Yue ;
Li, Gang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (43) :15586-+
[10]  
KIM CS, 2009, APPL PHYS LETT, V11