Oxygen selective ceramic hollow fiber membranes

被引:161
作者
Liu, SM [1 ]
Gavalas, GR [1 ]
机构
[1] CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA
关键词
hollow fiber; inorganic membrane; Ba0.5Sr0.5Co0.8Fe0.2O3-delta; perovskite; oxygen separation;
D O I
10.1016/j.memsci.2004.09.028
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Oxygen ion conducting Ba0.5Sr0.5Co0.8Fe0.2O3-delta hollow fiber membranes with o.d. 1. 15 mm and i.d. 0.71 mm were fabricated using a sequence of extrusion, gelation, coating and sintering steps. The starting ceramic powder was synthesized by combined EDTA-citrate complexing followed by thermal treatment at 900degreesC. The powder was then dispersed in a polymer solution, and extruded through a spinerette. After gelation, an additional thin coating of the ceramic powder was applied on the fiber, and sintering was carried out at 1190degreesC to obtain the final ceramic membrane. The fibers were characterized by SEM, and tested for air separation at ambient pressure and at temperatures between 700 and 950degreesC. The maximum oxygen flux measured was 5.1 mL/min/cm(2) at 950degreesC. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:103 / 108
页数:6
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