From polynorbornene to the complementary polynorbornene by replication

被引：68

作者：

Lin, Nai-Ti

Lin, Shu-Yi

Lee, Shern-Long

Chen, Chun-hsien

Hsu, Chao-Hsiung

Hwang, Lian Pin

Xie, Zhen-Yu

Chen, Chung-Hsuan

Huang, Shou-Ling

Luh, Tien-Yau ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan

[2] Acad Sinica, Inst Atom & Mol Sci, Taipei 106, Taiwan

[3] Acad Sinica, Genom Res Ctr, Taipei 115, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 24期

关键词：

ferrocenes; polynorbornenes; replication; ring-opening polymerization; scanning tunneling microscopy;

D O I：

10.1002/anie.200700472

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In undergoing a DNA-like replication process, the single-stranded polynorbornene acts as a template for norbornene monomer adhesion through ester linkages (see scheme). Polymerization of the adhered monomers affords the corresponding unsymmetric double-stranded polymer, which produces a complementary polynorbornene carboxylic acid after hydrolysis. The overall process involves a pass of information from the template polymer to the daughter polymer. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4481 / 4485

页数：5

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