Vapour pressures and enthalpies of vapourization of a series of the linear aliphatic nitriles

被引：49

作者：

Emel'yanenko, VN

Verevkin, SP

Koutek, B

Doubsky, J

机构：

[1] Univ Rostock, Fac Chem, Dept Phys Chem, D-18051 Rostock, Germany

[2] Acad Sci Czech Republ, Inst Organ Chem & Biochem, Prague, Czech Republic

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 2005年 / 37卷 / 01期

关键词：

aliphatic nitrites; transpiration method; vapour pressure; enthalpy of vapourization; Kovat's index;

D O I：

10.1016/j.jct.2004.08.004

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapour pressures and the molar enthalpies of vapourization Delta(1)(g)Hdegrees(m) of the linear aliphatic nitrites C-7-C-17 have been determined by the transpiration method. Kovat's indices of these compounds were measured by capillary gas-chromatography. A linear correlation of enthalpies of vapourization Delta(1)(g)Hdegrees(m) at T = 298.15 K of the nitriles studied with the Kovats indices has been found. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：73 / 81

页数：9

共 21 条

[1] ENTHALPIES OF COMBUSTION AND FORMATION OF ACETONITRILE [J].