Chemically powered nanodimers

被引:248
作者
Ruckner, Gunnar [1 ]
Kapral, Raymond [1 ]
机构
[1] Univ Toronto, Dept Chem, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada
关键词
D O I
10.1103/PhysRevLett.98.150603
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Self-propelled motion of a chemically powered nanodimer is discussed. The nanodimer comprises two linked spheres, one of which has equal interactions with A and B solvent species but catalyzes the reaction A -> B. The other sphere is not chemically active but interacts differently with the two species. The nonequilibrium concentration gradient generated at the catalytic end, in conjunction with the force difference at the noncatalytic end, leads to directed motion. The model mimics features of experimentally studied synthetic nanorod motion. Particle-based simulations and analytical estimates of the velocity provide insight into the nature of nanomotor directed motion.
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页数:4
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