Rational design of azide-bridged bimetallic complexes.: Crystal structure and magnetic properties of FeIIIMFeIII (M = NiII and CuII) trinuclear species

被引:51
作者
Colacio, E [1 ]
Costes, JP
Domínguez-Vera, JM
Ben Maimoun, I
Suárez-Varela, J
机构
[1] Univ Granada, Fac Ciencias, Dept Quim Inorgan, E-18071 Granada, Spain
[2] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France
[3] Univ Terouan, Fac Sci Mhannech, Dept Chem, Terouan, Morocco
关键词
D O I
10.1039/b413433h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first examples of azide-bridged bimetallic trinuclear complexes {[M(cyclam)][FeL(N-3)(mu(1,5)-N-3)](2)} (H2L = 4,5-dichloro-1,2-bis(pyridine-2-carboxamido) benzene) have been structurally and magnetically characterized.
引用
收藏
页码:534 / 536
页数:3
相关论文
共 19 条
[1]   [Cr(bipy)(C2O4)(2)](-) - A versatile building block for the design of heteropolymetallic systems .2. Syntheses and crystal structures of CuCr2(bipy)(2)(mu-C2O4)(2)(C2O4)(2)(H2O)(2)center dot 1(1)/2H2O and (AgCr(bipy)(mu-C2O4)(2)(H2O)(2))(2) and magnetic properties of the copper(II) derivative [J].
Andruh, M ;
Melanson, R ;
Stager, CV ;
Rochon, FD .
INORGANICA CHIMICA ACTA, 1996, 251 (1-2) :309-317
[2]   Homo- and hetero-polymetallic exchange coupled metal-oximates [J].
Chaudhuri, P .
COORDINATION CHEMISTRY REVIEWS, 2003, 243 (1-2) :143-190
[3]   SYNTHESIS, ELECTROCHEMISTRY, AND MAGNETIC AND SPECTROSCOPIC PROPERTIES OF AN EXCHANGE-COUPLED FEIIINIIIFEIII COMPLEX - CRYSTAL-STRUCTURE OF [L2FE2(DMG)3NI](PF6)2.0.5CH3OH (L = 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE - DMG = DIMETHYLGLYOXIMATE(2-)) [J].
CHAUDHURI, P ;
WINTER, M ;
DELLAVEDOVA, BPC ;
FLEISCHHAUER, P ;
HAASE, W ;
FLORKE, U ;
HAUPT, HJ .
INORGANIC CHEMISTRY, 1991, 30 (25) :4777-4783
[4]   Synthesis, structures, and magnetic properties of novel mononuclear, tetranuclear, and 1D chain MnIII complexes involving three related asymmetrical trianionic ligands [J].
Costes, JP ;
Dahan, F ;
Donnadieu, B ;
Douton, MJR ;
García, MIF ;
Bousseksou, A ;
Tuchagues, JP .
INORGANIC CHEMISTRY, 2004, 43 (08) :2736-2744
[5]   1,2-bis(pyridine-2-carboxamido)benzenate(2-), (bpb)2-:: A noninnocent ligand.: Syntheses, structures, and mechanisms of formation of [(n-Bu)4N][FeIV2(μ-N)(bpb)2(X)2] (X = CN-, N3-) and the electronic structures of [MIII(bpbox1)(CN)2] (M = Co, Fe) [J].
Dutta, SK ;
Beckmann, U ;
Bill, E ;
Weyhermüller, T ;
Wieghardt, K .
INORGANIC CHEMISTRY, 2000, 39 (15) :3355-3364
[6]   TRANS-[NI(333-TET)(MU-N3)]N(CLO4)N AND CIS-[NI(333-TET)(MU-N3)]N(PF6)N - 2 NOVEL KINDS OF STRUCTURAL NICKEL(II) CHAINS WITH A SINGLE AZIDO BRIDGE - MAGNETIC-BEHAVIOR OF AN ALTERNATING S=1 CHAIN WITH ALPHA=0.46 [J].
ESCUER, A ;
VICENTE, R ;
RIBAS, J ;
ELFALLAH, MS ;
SOLANS, X ;
FONTBARDIA, M .
INORGANIC CHEMISTRY, 1994, 33 (09) :1842-1847
[7]   Two-dimensional homochiral manganese(II)-azido frameworks incorporating an achiral ligand: Partial spontaneous resolution and weak ferromagnetism [J].
Gao, EQ ;
Bai, SQ ;
Wang, ZM ;
Yan, CH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (17) :4984-4985
[8]   Oxamato-bridged trinuclear NiIICuIINiII complexes with irregular spin state structures and a binuclear NiIICuII complex with an unusual supramolecular structure:: Crystal structure and magnetic properties [J].
Gao, EQ ;
Tang, JK ;
Liao, DZ ;
Jiang, ZH ;
Yan, SP ;
Wang, GL .
INORGANIC CHEMISTRY, 2001, 40 (13) :3134-3140
[9]  
Hong CS, 1999, ANGEW CHEM INT EDIT, V38, P193, DOI 10.1002/(SICI)1521-3773(19990115)38:1/2<193::AID-ANIE193>3.0.CO
[10]  
2-E