Polymorphism in hydrogen bonded frameworks; cyanuric acid-bis(4-pyridyl)ethene adducts

被引:23
作者
Barnett, SA [1 ]
Blake, AJ [1 ]
Champness, NR [1 ]
机构
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
关键词
D O I
10.1039/b303338d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structures of two polymorphic hydrogen bonded networks formed by cyanuric acid ( CA) and bis(4-pyridyl) ethene (bpe) are described. In both instances two-dimensional sheets are constructed from CA chains that are cross-linked by bpe moieties. Although all the sheets in both compounds adopt essentially equivalent hydrogen bonding connectivity, two different sheet arrangements are observed due to subtle variations in the N-H...O hydrogen bonds between CA molecules. In one polymorph only one type of sheet is observed while in the other both sheet arrangements occur.
引用
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页码:134 / 136
页数:3
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