Organometallic photochemistry at the end of its first century

被引:43
作者
Bitterwolf, TE [1 ]
机构
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
关键词
organometallic photochemistry; carbonyl loss; metal metal bond homolysis; time resolved spectroscopy; matrix isolation;
D O I
10.1016/j.jorganchem.2004.06.023
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The discovery of the light initiated reaction of Fe(CO)(5) to yield Fe-2(CO)(9) by Dewar and Jones in 1905 ushered in an era of the use of light to drive chemical reactions. This review seeks to examine selective chapters in this story by examining particularly significant reaction types in the context of their historical development. (C) 2004 Elsevier B.V. All rights reserved.
引用
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页码:3939 / 3952
页数:14
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