Electrosynthesis and coordination chemistry of poly(ferrocene-bipyridyl) films

被引：15

作者：

Buda, M

Moutet, JC

Pailleret, A

Saint-Aman, E

Ziessel, R

机构：

[1] Univ Grenoble 1, CNRS, UMR 5630, Lab Electrochim Organ & Photochim Redox, F-38041 Grenoble 9, France

[2] Univ Strasbourg 1, Ecole Chim Polymeres & Mat, ESA 7008, Lab Chim Elect & Photon Mol, F-67008 Strasbourg, France

[3] Polytech Univ, Dept Appl Phys Chem & Electrochem, Bucharest, Romania

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2000年 / 484卷 / 02期

关键词：

electrochemical recognition; redox-active receptors; functionalized polypyrrole; ferrocene-bipyridyl ligand; copper and nickel complexes;

D O I：

10.1016/S0022-0728(00)00073-5

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The pyrrole-containing 1,1'-bis(bipyridyl)-substituted derivative of ferrocene L exhibits electrochemical recognition properties towards Cu-I and Ni-II in homogeneous solution. PolyL films synthesised by its oxidative electropolymerisation are able to coordinate Cu-I ions, whereas they do not display coordinating ability for Ni-II. In contrast, electropolymerisation of L in the presence of Cu-I or Ni-II ions readily obtain pre-structured metallated films. These films can be demetallated electrochemically, and then partially remetallated. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：164 / 171

页数：8

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