Hydrogen adsorption on a single-walled carbon nanotube material:: a comparative study of three different adsorption techniques

被引:37
作者
Ansón, A
Benham, M
Jagiello, J
Callejas, MA
Benito, AM
Maser, WK
Züttel, A
Sudan, P
Martínez, MT
机构
[1] CSIC, Inst Carboquim, Zaragoza 50018, Spain
[2] Hiden Isochema Ltd, Sorpt Technol Div, Warrington WA5 7UN, Cheshire, England
[3] Quantachrome Instruments, Boynton Beach, FL 33426 USA
[4] Univ Fribourg, Dept Phys, CH-1700 Fribourg, Switzerland
关键词
D O I
10.1088/0957-4484/15/11/023
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Hydrogen adsorption measurements on mixed carbon material containing single-walled carbon nanotubes (SWNTs) obtained by the electric-arc method were carried out by three different techniques: a volumetric system, a gravimetric system and an electrochemical method. The found H-2 gas adsorption capacity (volumetric and gravimetric) is very low, around 0.01 wt% at room temperature and pressure, increasing to 0.1 wt% at 20 bar. Electrochemical measurements show a slightly higher capacity (0.1-0.3 wt%) than volumetric and gravimetric data. The results obtained by the three different techniques are compatible within each other and they are also in good agreement with other previously reported data from different researchers.
引用
收藏
页码:1503 / 1508
页数:6
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