Correlation between photovoltaic performance and impedance spectroscopy of dye-sensitized solar cells based on ionic liquids

被引:865
作者
Fabregat-Santiago, Francisco
Bisquert, Juan
Palomares, Emilio
Otero, Luis
Kuang, Daibin
Zakeeruddin, Shaik M.
Gratzel, Michael
机构
[1] Univ Jaume 1, Dept Fis, Castellon de La Plana 12071, Spain
[2] Inst Chem Res Catalonia ICIQ, Tarragona 430070, Spain
[3] Univ Nacl Rio Cuarto, Dept Quim, RA-5800 Rio Cuarto, Argentina
[4] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
关键词
D O I
10.1021/jp066178a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, we study the characteristics of dye-sensitized solar cells using an ionic liquid as the electrolyte and compare them with the response of a solvent-containing electrolyte cell. Impedance spectroscopy is used to derive the key circuit elements determining the photovoltaic performance of the cell. On the basis of this data, photocurrent voltage curves are calculated and compared with experimental results.
引用
收藏
页码:6550 / 6560
页数:11
相关论文
共 36 条
  • [1] Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies
    Bach, U
    Lupo, D
    Comte, P
    Moser, JE
    Weissörtel, F
    Salbeck, J
    Spreitzer, H
    Grätzel, M
    [J]. NATURE, 1998, 395 (6702) : 583 - 585
  • [2] Chemical capacitance of nanostructured semiconductors: its origin and significance for nanocomposite solar cells
    Bisquert, J
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (24) : 5360 - 5364
  • [3] Effect of energy disorder in interfacial kinetics of dye-sensitized solar cells with organic hole transport material
    Bisquert, Juan
    Palomares, Emilio
    Quinones, Cesar A.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (39) : 19406 - 19411
  • [4] Hydrophobic, highly conductive ambient-temperature molten salts
    Bonhote, P
    Dias, AP
    Papageorgiou, N
    Kalyanasundaram, K
    Gratzel, M
    [J]. INORGANIC CHEMISTRY, 1996, 35 (05) : 1168 - 1178
  • [5] Non-haloaluminate room-temperature ionic liquids in electrochemistry - A review
    Buzzeo, MC
    Evans, RG
    Compton, RG
    [J]. CHEMPHYSCHEM, 2004, 5 (08) : 1106 - 1120
  • [6] A SOLID-STATE, DYE-SENSITIZED PHOTOELECTROCHEMICAL CELL
    CAO, F
    OSKAM, G
    SEARSON, PC
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (47) : 17071 - 17073
  • [7] Dye-sensitized solar cells with conversion efficiency of 11.1%
    Chiba, Yasuo
    Islam, Ashraful
    Watanabe, Yuki
    Komiya, Ryoichi
    Koide, Naoki
    Han, Liyuan
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (24-28): : L638 - L640
  • [8] Chemical capacitance of nanoporous-nanocrystalline TiO2 in a room temperature ionic liquid
    Fabregat-Santiago, F
    Randriamahazaka, H
    Zaban, A
    Garcia-Cañadas, J
    Garcia-Belmonte, G
    Bisquert, J
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (15) : 1827 - 1833
  • [9] Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy
    Fabregat-Santiago, F
    Bisquert, J
    Garcia-Belmonte, G
    Boschloo, G
    Hagfeldt, A
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 87 (1-4) : 117 - 131
  • [10] Hybrid solar cells based on dye-sensitized nanoporous TiO2 electrodes and conjugated polymers as hole transport materials
    Gebeyehu, D
    Brabec, CJ
    Sariciftci, NS
    Vangeneugden, D
    Kiebooms, R
    Vanderzande, D
    Kienberger, F
    Schindler, H
    [J]. SYNTHETIC METALS, 2001, 125 (03) : 279 - 287