A novel integrated process for the functionalization of methane and ethane: bromine as mediator

被引：35

作者：

Lorkovic, IM ^{[1
]}

Yilmaz, A

Yilmaz, GA

Zhou, XP

Laverman, LE

Sun, SL

Schaefer, DJ

Weiss, M

Noy, ML

Cutler, CI

Sherman, JH

McFarland, EW

Stucky, GD

Ford, PC

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

[2] GRT Inc, Santa Barbara, CA 93111 USA

[3] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA

来源：

CATALYSIS TODAY | 2004年 / 98卷 / 1-2期

关键词：

bromine-mediated; partial oxidation; alkane; metal oxide;

D O I：

10.1016/j.cattod.2004.07.058

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

We describe a novel, integrated multi-step process for the partial oxidation of alkanes to alcohols, ethers or olefins using O-2 as oxidant. The sequential transformations are (1) alkane bromination to alkyl bromide(s) and HBr, (2) reaction of this mixture with solid metal oxide (MO) to neutralize the HBr and to generate oxygenated products or olefins plus solid metal bromide, and (3) oxidation of the spent solid with 02 to regenerate the metal oxide and Br-2 for reuse. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：317 / 322

页数：6

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