Wacker oxidation in an aqueous phase through the reverse phase-transfer catalysis of a self-assembled nanocage

被引：127

作者：

Ito, H

Kusukawa, T ^{[1
]}

Fujita, M

机构：

[1] Grad Univ Adv Studies, Okazaki, Aichi 4448585, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[3] Japan Sci & Technol Corp, CREST, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 06期

关键词：

D O I：

10.1246/cl.2000.598

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Self-assembled nanocage 1 was found to promote the aerobic, aqueous oxidation of styrene and its derivatives with the aid of(en)Pd(NO3)(2). Obviously, the reaction was promoted by a double catalysis system: i.e., cage 1 acted as a reverse phase-transfer catalyst, whereas (en)Pd2+ as an oxidation catalyst.

引用

收藏

页码：598 / 599

页数：2

相关论文

共 21 条

[1] Biomimetic reactions catalyzed by cyclodextrins and their derivatives [J].

Breslow, R ;

Dong, SD .

CHEMICAL REVIEWS, 1998, 98 (05) :1997-2011

[2] SELF-ASSEMBLY OF 10 MOLECULES INTO NANOMETER-SIZED ORGANIC HOST FRAMEWORKS [J].

FUJITA, M ;

OGURO, D ;

MIYAZAWA, M ;

OKA, H ;

YAMAGUCHI, K ;

OGURA, K .

NATURE, 1995, 378 (6556) :469-471

[3] CYCLODEXTRIN-PALLADIUM CHLORIDE - NEW CATALYTIC-SYSTEM FOR SELECTIVE OXIDATION OF OLEFINS TO KETONES [J].

HARADA, A ;

HU, Y ;

TAKAHASHI, S .

CHEMISTRY LETTERS, 1986, (12) :2083-2084

[4] WATER-SOLUBLE LIGANDS, METAL-COMPLEXES, AND CATALYSTS - SYNERGISM OF HOMOGENEOUS AND HETEROGENEOUS CATALYSIS [J].

HERRMANN, WA ;

KOHLPAINTNER, CW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (11) :1524-1544

[5]

HU Y, 1988, SYNTHETIC COMMUN, V18, P2083

[6] Diels-Alder reactions through reversible encapsulation [J].

Kang, JM ;

Hilmersson, G ;

Santamaría, J ;

Rebek, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (15) :3650-3656

[7] Acceleration of a Diels-Alder reaction by a self-assembled molecular capsule [J].

Kang, JM ;

Rebek, J .

NATURE, 1997, 385 (6611) :50-52

[8] Self-assembled molecular capsule catalyzes a Diels-Alder reaction [J].

Kang, JM ;

Santamaría, J ;

Hilmersson, G ;

Rebek, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (29) :7389-7390

[9] Lewis acid catalysts stable in water. Correlation between catalytic activity in water and hydrolysis constants and exchange rate constants for substitution of inner-sphere water ligands [J].

Kobayashi, S ;

Nagayama, S ;

Busujima, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (32) :8287-8288

[10]

KOBAYASHI S, 1991, CHEM LETT, P2087