Amplification of chirality by transition metal coordination:: synthesis of chiral allenes and allene manganese complexes of high enantiomeric purity.: Synthesis of methyl (R,E)-(-)-(2,4,5-tetradecatrienoate (pheromone of Acanthoscelides obtectus (say))

被引：22

作者：

Franck-Neumann, M ^{[1
]}

Martina, D ^{[1
]}

Neff, D ^{[1
]}

机构：

[1] Univ Strasbourg 1, Inst Chim, CNRS, Lab Chim Organ Synth, F-67008 Strasbourg, France

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 04期

关键词：

D O I：

10.1016/S0957-4166(98)00023-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enhancement of the asymmetry of chiral allenes by coordination with a transition metal can be turned to account for (easy) resolution of the complexes and therefore the allenes themselves. This is illustrated here on allene aldehyde complexes of (eta-methylcyclopentadienyl) dicarbonylmanganese, possibly bearing a second electron withdrawing substituent, and by the synthesis of an optically active alkenylallenic insect pheromone of high enantiomeric purity. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：697 / 708

页数：12

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