Transparent photocatalytic films deposited on polymer substrates from sol-gel processed titania sols

被引:57
作者
Langlet, M
Kim, A
Audier, M
Guillard, C
Herrmann, JM
机构
[1] INPG, ENSPG, CNRS, UMR 5628,Lab Mat & Genie Phys, F-38402 St Martin Dheres, France
[2] Ecole Cent Lyon, CNRS, UMR 5621, IFOS,Lab Photocatalyse Catalyse & Environm, F-69131 Ecully, France
关键词
sol-gel processing; basic peptization; photocatalytic TiO2 films; polymer substrates;
D O I
10.1016/S0040-6090(02)01290-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Titania sols were peptized in basic conditions and subsequently refluxed or autoclaved. Thin titania films were subsequently deposited using these sols. The microstructural, morphological, optical, and photocatalytic properties of the films were studied with respect to the sol-gel processing parameters. It is shown that basic peptization conditions lead to room temperature deposition of well crystallized and optical quality films. Consequently, transparent anatase films endowed with good photocatalytic properties could be deposited on polymer substrates. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:13 / 21
页数:9
相关论文
共 34 条
[1]   PHOTOCATALYTIC HYDROGENATION OF CH3CCH WITH H2O ON SMALL-PARTICLE TIO2 - SIZE QUANTIZATION EFFECTS AND REACTION INTERMEDIATES [J].
ANPO, M ;
SHIMA, T ;
KODAMA, S ;
KUBOKAWA, Y .
JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (16) :4305-4310
[2]   Rutile formation in hydrothermally crystallized nanosized titania [J].
Bacsa, RR ;
Gratzel, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (08) :2185-2188
[3]   PEPTIZATION PROCESS IN THE SOL-GEL PREPARATION OF POROUS ANATASE (TIO2) [J].
BISCHOFF, BL ;
ANDERSON, MA .
CHEMISTRY OF MATERIALS, 1995, 7 (10) :1772-1778
[4]  
BORN M, 1975, PRINCIPLES OPTICS, P87
[5]  
BRINKER CJ, 1990, SOL GEL SCI PHYS CHE, P194
[6]   Condensation and densification mechanism of sol-gel TiO2 layers at low temperature [J].
Burgos, M ;
Langlet, M .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1999, 16 (03) :267-276
[7]  
*CHEM RUBB CO, 1967, HDB CHEM PHYS, pB279
[8]  
Chemseddine A, 1999, EUR J INORG CHEM, P235, DOI 10.1002/(SICI)1099-0682(19990202)1999:2<235::AID-EJIC235>3.0.CO
[9]  
2-N
[10]   Preparation and characterization of TiO2 photocatalysts supported on various rigid supports (glass, quartz and stainless steel). Comparative studies of photocatalytic activity in water purification [J].
Fernandez, A ;
Lassaletta, G ;
Jimenez, VM ;
Justo, A ;
GonzalezElipe, AR ;
Herrmann, JM ;
Tahiri, H ;
AitIchou, Y .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1995, 7 (1-2) :49-63