On the reaction of a dioxenylmolybdenum carbene complex with enynes: Studies of the intramolecular Diels-Alder reaction

被引：18

作者：

Harvey, DF

Grenzer, EM

机构：

[1] Dept. of Chemistry and Biochemistry, University of California, San Diego, San Diego, CA 92093-0358

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1996年 / 61卷 / 01期

关键词：

D O I：

10.1021/jo9513370

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dioxenylmolybdenum carbene complex 1 has been found to readily react with enynes to form tetracyclic products. The tetracyclic products of this reaction appear to be generated via intramolecular [4 + 2] cycloaddition of an initially formed trialkoxycyclopentadiene derivative. Studies which help to define the generality of this reaction are reported, and the involvement of the metal in the cyclization process is discussed.

引用

页码：159 / 165

页数：7

共 59 条

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