Total synthesis of (+)-furanomycin

被引:45
作者
Kang, SH [1 ]
Lee, SB [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Taejon 305701, South Korea
关键词
D O I
10.1039/a800727f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly enantioselective total synthesis of (+)-furanomycin 24 has been achieved via the mercury cation-mediated cyclizations of gamma-hydroxy alkene 4 and homoallylic trichloroacetimidate 11 to install the trans-2,5-disubstituted tetrahydrofuran and the (alpha S)-amino acid side chain, respectively.
引用
收藏
页码:761 / 762
页数:2
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