Bis(η5-methyl-cyclopentadienyl)-bis(cyanato)vanadium(IV)

被引：7

作者：

Honzícek, J

Erben, M

Císarová, L

Vinklárek, J

机构：

[1] Univ Pardubice, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic

[2] Charles Univ Prague, Dept Inorgan Chem, CR-12840 Prague 2, Czech Republic

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 01期

关键词：

methyl-cyclopentadienyl; vanadocene; pseudohalide; crystal structure;

D O I：

10.1002/aoc.663

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The crystal structure of the first cyclopentadienyl. vanadium(IV) pseudohalide complex, (n(5)- C5H4CH3)(2)V(NCO)(2), was determined. The molecule has a typical bent metallocene structure in which two n(5)-bonded methyl-cyclopentadienyl rings and two nitrogen atoms of cyanato ligands occupy the pseudotetrahedral coordination sites around the vanadium(IV) center. Copyright (C) 2004 John Wiley Sons, Ltd.

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页码：100 / 101

页数：2

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