Regioselective dendritic functionalization of cellulose

被引:42
作者
Hassan, ML
Moorefield, CN
Newkome, GR [1 ]
机构
[1] Univ Akron, Maurice Morton Inst Polymer Sci, Akron, OH 44325 USA
[2] Univ Akron, Dept Chem, Akron, OH 44325 USA
[3] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
[4] Natl Res Ctr, Cellulose & Paper Dept, Cairo 12622, Egypt
关键词
cellulose; dendron; dendronized polymer; isocyanate; regioselective; thermogravimetric analysis (TGA);
D O I
10.1002/marc.200400423
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A series of regioselectively dendronized cellulose derivatives has been prepared by the treatment of cellulose in a N,N-dimethylacetamide/LiCl solvent system with dendrons possessing isocyanate focal substituents. These new materials were characterized using FT-IR and C-13 NMR spectroscopies, and thermogravimetric analysis; the products were highly soluble in a wide range of organic solvents.
引用
收藏
页码:1999 / 2002
页数:4
相关论文
共 18 条
[1]   Regioselective nitrilotriacetic acid-cellulose-nickel-complexes for immobilisation of His6-tag proteins [J].
Diekmann, S ;
Siegmund, G ;
Roecker, A ;
Klemm, DO .
CELLULOSE, 2003, 10 (01) :53-63
[2]  
Elias H., 1997, INTRO POLYM SCI
[3]   Unconventional methods in cellulose functionalization [J].
Heinze, T ;
Liebert, T .
PROGRESS IN POLYMER SCIENCE, 2001, 26 (09) :1689-1762
[4]   Preparations of regioselectively methylated cellulose acetates and their 1H and 13C NMR spectroscopic analyses [J].
Karakawa, M ;
Mikawa, Y ;
Kamitakahara, H ;
Nakatsubo, F .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (23) :4167-4179
[5]  
KENNEDY AD, 1993, CELLULOSE STRUCTURE
[6]   New approaches to advanced polymers by selective cellulose functionalization [J].
Klemm, D ;
Heinze, T ;
Philipp, B ;
Wagenknecht, W .
ACTA POLYMERICA, 1997, 48 (08) :277-297
[7]  
KLEMM D, 1998, COMP CELLULOSE CHEM
[8]  
KLEMM D, 1998, COMP CELLULOSE CHEM, V1
[9]  
Newkome G.R., 1998, DES MONOMERS POLYM, V1, P3, DOI [10.1163/156855598X00071, DOI 10.1163/156855598X00071]
[10]   Synthesis and characterization of immobilized dendritic silica surfaces [J].
Newkome, GR ;
Yoo, KS ;
Moorefield, CN .
DESIGNED MONOMERS AND POLYMERS, 2002, 5 (01) :67-77