Time-resolved photoelectron angular distributions as a map of rotational motion

被引:13
作者
Seideman, T [1 ]
Althorpe, SC [1 ]
机构
[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
关键词
D O I
10.1016/S0368-2048(00)00131-6
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
We discuss the application of photoelectron angular distributions as a probe of time-evolving rovibrational wavepackets. A physical picture is drawn of the mechanism through which rotation-vibration coupling mechanisms are reflected in the time-dependent photoionisation asymmetry parameters. The effects of complicating features that may obscure the interpretation of time-resolved photoelectron spectroscopies, including the field intensity and the inherent complexity of ionisation processes are examined. (C) 2000 Elsevier Science BN. All rights reserved.
引用
收藏
页码:99 / 108
页数:10
相关论文
共 39 条
[1]   HIGH-RESOLUTION ANGLE-RESOLVED AND ENERGY-RESOLVED PHOTOELECTRON-SPECTROSCOPY OF NO - PARTIAL-WAVE DECOMPOSITION OF THE IONIZATION CONTINUUM [J].
ALLENDORF, SW ;
LEAHY, DJ ;
JACOBS, DC ;
ZARE, RN .
JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (04) :2216-2234
[2]  
ALLEY MR, 1988, J MOL SPECTROSC, V3, P1
[3]   Molecular alignment from femtosecond time-resolved photoelectron angular distributions: Nonperturbative calculations on NO [J].
Althorpe, SC ;
Seideman, T .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (01) :147-155
[4]  
ALTHORPE SC, UNPUB J CHEM PHYS
[5]   Femtosecond pump-probe photoelectron spectroscopy: Mapping of vibrational wave-packet motion [J].
Assion, A ;
Geisler, M ;
Helbing, J ;
Seyfried, V ;
Baumert, T .
PHYSICAL REVIEW A, 1996, 54 (06) :R4605-R4608
[6]   Coherent control with femtosecond laser pulses [J].
Baumert, T ;
Helbing, J ;
Gerber, G ;
Woste, L ;
Zewail, AH ;
Troe, J ;
Manz, J ;
Kobayashi, T ;
Letokhov, VS ;
Even, U ;
Chergui, M ;
Neumark, DM ;
Rice, SA .
CHEMICAL REACTIONS AND THEIR CONTROL ON THE FEMTOSECOND TIME SCALE XXTH SOLVAY CONFERENCE ON CHEMISTRY, 1997, 101 :47-82
[7]   Discerning vibronic molecular dynamics using time-resolved photoelectron spectroscopy [J].
Blanchet, V ;
Zgierski, MZ ;
Seideman, T ;
Stolow, A .
NATURE, 1999, 401 (6748) :52-54
[8]   Femtosecond real-time probing of reactions .21. Direct observation of transition-state dynamics and structure in charge-transfer reactions [J].
Cheng, PY ;
Zhong, D ;
Zewail, AH .
JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (15) :6216-6248
[9]   Femtosecond time-resolved photoionization and photoelectron spectroscopy studies of ultrafast internal conversion in 1,3,5-hexatriene [J].
Cyr, DR ;
Hayden, CC .
JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (02) :771-774
[10]   Femtosecond time-resolved photoelectron-photoion coincidence imaging studies of dissociation dynamics [J].
Davies, JA ;
LeClaire, JE ;
Continetti, RE ;
Hayden, CC .
JOURNAL OF CHEMICAL PHYSICS, 1999, 111 (01) :1-4