Spatially correlated nuclei: How the Johnson-Mekl-Avrami-Kolmogorov formula is modified in the case of simultaneous nucleation

被引:32
作者
Tomellini, M
Fanfoni, M
Volpe, M
机构
[1] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, I-00133 Rome, Italy
[2] Univ Roma Tor Vergata, Dipartimento Fis, I-00133 Rome, Italy
[3] Ist Nazl Fis Mat, I-00133 Rome, Italy
[4] ENEA, Div Nuovi Mat, Ctr Ric Casaccia, I-00100 Rome, Italy
关键词
D O I
10.1103/PhysRevB.62.11300
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present a theoretical investigation about the role played by spatial correlation among nuclei in the kinetics of first-order phase transitions. From the cluster expansion of the distribution functions in terms of the m-dots correlation functions, we obtain the equation which describes the kinetics in case of simultaneous nucleation. Truncation of the cluster expansion to the lowest order terms leads to an analytical solution. In order to test it we compare it to Monte Carlo simulations for the hard-core model, finding an excellent agreement. The theory is also applied to estimate the rate of random sequential adsorption of circular disks.
引用
收藏
页码:11300 / 11303
页数:4
相关论文
共 32 条
[1]   Kinetics of phase change I - General theory [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112
[2]  
Avrami M., 1940, J CHEM PHYS, V8, P212
[3]   SCALING RELATIONS FOR GRAIN AUTOCORRELATION FUNCTIONS DURING NUCLEATION AND GROWTH [J].
AXE, JD ;
YAMADA, Y .
PHYSICAL REVIEW B, 1986, 34 (03) :1599-1606
[4]   Adatom capture by arrays of two-dimensional Ag islands on Ag(100) [J].
Bartelt, MC ;
Stoldt, CR ;
Jenks, CJ ;
Thiel, PA ;
Evans, JW .
PHYSICAL REVIEW B, 1999, 59 (04) :3125-3134
[5]   KINETICS OF TRANSFORMATION FOR ANISOTROPIC PARTICLES INCLUDING SHIELDING EFFECTS [J].
BIRNIE, DP ;
WEINBERG, MC .
JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (09) :3742-3746
[6]   The time cone method for nucleation and growth kinetics on a finite domain [J].
Cahn, JW .
THERMODYNAMICS AND KINETICS OF PHASE TRANSFORMATIONS, 1996, 398 :425-437
[7]   Self-organization on semiconductor surfaces: fundamental thermodynamic issues [J].
Carlow, GR ;
Perovic, DD ;
Zinke-Allmang, M .
APPLIED SURFACE SCIENCE, 1998, 130 :704-712
[8]   Evaluation of time-dependent grain-size populations for nucleation and growth kinetics [J].
Crespo, D ;
Pradell, T .
PHYSICAL REVIEW B, 1996, 54 (05) :3101-3109
[9]   Demonstration of Avrami's kinetics: Connection with rate equations for clustering on surfaces [J].
Fanfoni, M ;
Tomellini, M .
PHYSICAL REVIEW B, 1996, 54 (14) :9828-9833
[10]  
HANSEN J. P., 2013, Theory of Simple Liquids