Weakly coupled radical pairs in solids: ELDOR in ESE structure studies

被引:41
作者
Maryasov, AG [1 ]
Tsvetkov, YD
Raap, J
机构
[1] Russian Acad Sci, Inst Chem Kinet & Combust, Novosibirsk 630090, Russia
[2] Leiden Univ, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
关键词
D O I
10.1007/BF03162010
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Possibilities of the structure determination of radical pairs having fixed geometry with the help of ELDOR in ESE technique are considered. It is demonstrated that one can obtain information on relative orientation of paramagnetic centers in weakly coupled pairs in addition to the energy parameters of the spin Hamiltonian. Appropriate requirements for such experiments are formulated.
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页码:101 / 113
页数:13
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