A highly selective and sensitive fluorescent chemosensor for Fe3+ in physiological aqueous solution

被引:40
作者
Hua, J [1 ]
Wang, YG [1 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
关键词
D O I
10.1246/cl.2005.98
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel fluorescent chemosensor in which two aza-18-crown-6 moieties are linked to a coumarin fluorophore has been synthesized for sensing Fe3+. The selective fluorescence enhancement was observed upon binding Fe3+ at physiological conditions (pH=7.4, [NaCl]=0.135M, [KCl]=0.01M), whereas other metal ions, such as Li+, Na+, K+, Mg2+, Ca2+, Cu2+, Zn2+, Co2+, Ni2+, Mn2+, Hg2+ and Pb2+ produced no effect.
引用
收藏
页码:98 / 99
页数:2
相关论文
共 23 条
[1]   Anion recognition by dimetallic cryptates [J].
Amendola, V ;
Fabbrizzi, L ;
Mangano, C ;
Pallavicini, P ;
Poggi, A ;
Taglietti, A .
COORDINATION CHEMISTRY REVIEWS, 2001, 219 :821-837
[2]   SUBSTITUTED COUMARINS AND AZACOUMARINS - SYNTHESIS AND FLUORESCENT PROPERTIES [J].
ATKINS, RL ;
BLISS, DE .
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (10) :1975-1980
[3]   Fluorescent sensors for Zn2+ based on a fluorescein platform:: Synthesis, properties and intracellular distribution [J].
Burdette, SC ;
Walkup, GK ;
Spingler, B ;
Tsien, RY ;
Lippard, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (32) :7831-7841
[4]   A highly selective fluorescent chemosensor for lead ions [J].
Chen, CT ;
Huang, WP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) :6246-6247
[5]  
Fabbrizzi L, 2002, ANGEW CHEM INT EDIT, V41, P3811, DOI 10.1002/1521-3773(20021018)41:20<3811::AID-ANIE3811>3.0.CO
[6]  
2-W
[7]   Crown ethers: Sensors for ions and molecular scaffolds for materials and biological models [J].
Gokel, GW ;
Leevy, WM ;
Weber, ME .
CHEMICAL REVIEWS, 2004, 104 (05) :2723-2750
[8]   Cd(II) sensing in water using novel aromatic iminodiacetate based fluorescent chemosensors [J].
Gunnlaugsson, T ;
Lee, TC ;
Parkesh, R .
ORGANIC LETTERS, 2003, 5 (22) :4065-4068
[9]   A highly selective and sensitive fluorescent chemosensor for Hg2+ in neutral buffer aqueous solution [J].
Guo, XF ;
Qian, XH ;
Jia, LH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (08) :2272-2273
[10]  
Han MS, 2002, ANGEW CHEM INT EDIT, V41, P3809, DOI 10.1002/1521-3773(20021018)41:20<3809::AID-ANIE3809>3.0.CO