The collision-energy/electron-energy-resolve two-dimensional Penning ionization electron spectrum for N-2/He*(2(3)S) was observed in the collision-energy range 70-380 meV. A large peak shift to higher electron energies and band width broadening were observed for the A state with increase of collision energy in comparison to those for the X and B states. Branching ratios for the three ionic states of N-2(+) as a continuous function of collision energy were investigated. The order of the branching ratios changes from B > X > A to A > B > X in the 100-200 meV collision energy region. (C) 1998 Elsevier Science B.V.