High resolution synchrotron radiation PES study of PbPc deposited on Pt(111)

被引：18

作者：

Papageorgiou, N ^{[1
]}

Mossoyan, JC

Mossoyan-Deneux, M

Terzian, G

Janin, E

Göthelid, M

Giovanelli, L

Layet, JM

Le Lay, G

机构：

[1] Univ Aix Marseille 1, PIIM UMR 6633, CNRS, F-13397 Marseille 20, France

[2] Univ Aix Marseille 1, LCC, F-13397 Marseille, France

[3] Royal Inst Technol, Dept Phys Mat, S-10044 Stockholm, Sweden

[4] CNRS, CRMC2, F-13288 Marseille, France

来源：

APPLIED SURFACE SCIENCE | 2000年 / 162卷

关键词：

organic-semiconductors; semiconducting thin films; lead phthalocyanine; metal-organic molecule interface; synchrotron radiation photoelectron spectroscopy;

D O I：

10.1016/S0169-4332(00)00189-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We studied lead phthalocyanine (PbPc) films sublimated under UHV conditions on a clean Pt(111) substrate. We report results from high resolution photoelectron spectra of the Pb 5d, Ph 4f, C 1s, N 1s and Pt 4f core level using synchrotron radiation. Comparison between ultra thin films and thicker films shows that the first molecular adlayer interacts strongly with the substrate and we report evidence of Pb-Pt alloy formation on the surface. For the thick films, the C Is and N Is core level spectra show usual characteristics, however in the case of ultra thin films, we note important differences with respect to some previous results. (C) 2000 Elsevier Science B,V. All rights reserved.

引用

页码：178 / 183

页数：6

共 17 条

[1]

CHASTAIN G, 1992, PHI HDB XRAY PHOTOEL

[2]

DONIACH S, 1970, J PHYS C SOLID STATE, V3, P185

[3] COPPER PHTHALOCYANINE ON SI(111)-7X7 AND SI(001)-2X1 SURFACES - AN X-RAY PHOTOEMISSION SPECTROSCOPY AND SYNCHROTRON X-RAY-ABSORPTION SPECTROSCOPY STUDY [J].

DUFOUR, G ;

PONCEY, C ;

ROCHET, F ;

ROULET, H ;

SACCHI, M ;

DESANTIS, M ;

DECRESCENZI, M .

SURFACE SCIENCE, 1994, 319 (03) :251-266

[4] X-RAY PHOTOELECTRON-SPECTROSCOPY OF CLEAN AND GAS-DOPED FILMS OF PHTHALOCYANINES [J].

EWEN, RJ ;

HONEYBOURNE, CL .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1991, 3 :S303-S310

[5] CORE-LEVEL BINDING-ENERGIES IN METALS [J].

FUGGLE, JC ;

MARTENSSON, N .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1980, 21 (03) :275-281

[6] SURFACE-ANALYSIS ON LEAD PHTHALOCYANINE WITH STM [J].

HAMANN, C ;

LAIHO, R ;

MRWA, A .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1989, 116 (02) :729-734

[7]

Kim JW, 1997, J ELECTRON SPECTROSC, V85, P35, DOI 10.1016/S0368-2048(96)03094-0

[8]

NIWA Y, 1974, INORG CHEM, V13, P2891, DOI 10.1021/ic50142a024

[9]

NIWA Y, 1974, J CHEM PHYS, V60, P799, DOI 10.1063/1.1681153

[10] PbPC growth on Si surfaces studied with XPS and various SPM techniques [J].

Ottaviano, L ;

Lozzi, L ;

Santucci, S ;

DiNardo, S ;

Passacantando, M .

SURFACE SCIENCE, 1997, 392 (1-3) :52-61

← 1 2 →