Anisotropic photoionisation and dissociation through inner valence states of the O2+ and NO+ ions

被引:44
作者
Eland, JHD [1 ]
Duerr, EJ [1 ]
机构
[1] Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
关键词
D O I
10.1016/S0301-0104(97)00331-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Spectra of energy-analysed photoelectrons in coincidence with energetic ion fragments from dissociative ionisation of O-2 and NO at 30.4 nm are analysed to give dissociation channel branching ratios and oriented-molecule photoelectron angular distributions. Anisotropic electron angular distributions are found in formation of the B-2 Sigma(-), 3(2) Pi(u) and (2) Sigma(u)(-) states of O-2(+), the c(3) Pi and B'(1) Sigma(+) states of NO+ and in formation of several unidentified higher-energy states of both molecular ions by 30.4 nm photoionisation. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:1 / 11
页数:11
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