Electroluminescent devices from ionic transition metal complexes

被引:318
作者
Slinker, Jason D.
Rivnay, Jonathan
Moskowitz, Joshua S.
Parker, Jeffrey B.
Bernhard, Stefan
Abruna, Héctor D.
Malliaras, George G. [1 ]
机构
[1] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
[2] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
[3] Cornell Univ, Dept Chem & Biol Chem, Ithaca, NY 14853 USA
基金
美国国家科学基金会;
关键词
D O I
10.1039/b704017b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ionic transition metal complexes (iTMCs) are receiving increased attention as materials capable of yielding efficient electroluminescent devices with air-stable electrodes. The operational characteristics of these devices are dominated by the presence of mobile ions that redistribute under an applied bias and assist in electronic charge injection. This article reviews recent efforts in the field of iTMC devices: i) to understand their physics, ii) to improve their efficiency, colour, turn-on time and lifetime, and iii) to expose their potential applications.
引用
收藏
页码:2976 / 2988
页数:13
相关论文
共 79 条
[1]   Highly luminescent CuI complexes for light-emitting electrochemical cells [J].
Armaroli, Nicola ;
Accorsi, Gianluca ;
Holler, Michel ;
Moudam, Omar ;
Nierengarten, Jean-Francois ;
Zhou, Zhongyuan ;
Wegh, Rene T. ;
Welter, Richard .
ADVANCED MATERIALS, 2006, 18 (10) :1313-1316
[2]   Electroluminescence in ruthenium(II) dendrimers [J].
Barron, JA ;
Bernhard, S ;
Houston, PL ;
Abruña, HD ;
Ruglovsky, JL ;
Malliaras, GG .
JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (40) :8130-8133
[3]   The promise and challenge of solid-state lighting [J].
Bergh, A ;
Craford, G ;
Duggal, A ;
Haitz, R .
PHYSICS TODAY, 2001, 54 (12) :42-47
[4]   Cascaded light-emitting devices based on a ruthenium complex [J].
Bernards, DA ;
Slinker, JD ;
Malliaras, GG ;
Flores-Torres, S ;
Abruña, HD .
APPLIED PHYSICS LETTERS, 2004, 84 (24) :4980-4982
[5]   Organic light-emitting devices with laminated top contacts [J].
Bernards, DA ;
Biegala, T ;
Samuels, ZA ;
Slinker, JD ;
Malliaras, GG ;
Flores-Torres, S ;
Abruña, HD ;
Rogers, JA .
APPLIED PHYSICS LETTERS, 2004, 84 (18) :3675-3677
[6]   Observation of electroluminescence and photovoltaic response in ionic junctions [J].
Bernards, Daniel A. ;
Flores-Torres, Samuel ;
Abruna, Hector D. ;
Malliaras, George G. .
SCIENCE, 2006, 313 (5792) :1416-1419
[7]   Electroluminescence in ruthenium(II) complexes [J].
Bernhard, S ;
Barron, JA ;
Houston, PL ;
Abruña, HD ;
Ruglovksy, JL ;
Gao, XC ;
Malliaras, GG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (45) :13624-13628
[8]  
Bernhard S, 2002, ADV MATER, V14, P433, DOI 10.1002/1521-4095(20020318)14:6<433::AID-ADMA433>3.0.CO
[9]  
2-W
[10]   Observation of intermediate-range order in a nominally amorphous molecular semiconductor film [J].
Blasini, Daniel R. ;
Rivnay, Jonathan ;
Smilgies, Detlef-M. ;
Slinker, Jason D. ;
Flores-Torres, Samuel ;
Abruna, Hector D. ;
Malliaras, George G. .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (15) :1458-1461