Self-assembled architectures from glycoluril

被引：75

作者：

Elemans, JAAW ^{[1
]}

Rowan, AE ^{[1
]}

Nolte, RJM ^{[1
]}

机构：

[1] Univ Nijmegen, Dept Organ Chem, NSR Ctr, NL-6525 ED Nijmegen, Netherlands

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2000年 / 39卷 / 10期

关键词：

D O I：

10.1021/ie000079g

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The controlled self-assembly of derivatives of the concave building block glycoluril into three-dimensional architectures of well-defined shape and dimension is discussed. It is-shown that the hexameric glycoluril macrocycle cucurbituril can be applied to construct a variety of oligo- and polyrotaxane assemblies. In a different approach, bis(glycoluril) compounds have been used to form "tennis ball"- and "softball"-like assemblies which can complex small guest molecules in their inner compartment and carry out reactions between them. Finally,the self-assembling properties of molecular clip receptors based on glycoluril are discussed. These clips can be modified in such a way that assemblies of well-defined shape and nanosized dimension, such as "golf balls", "razorblades", and "cigars", are formed in water.

引用

页码：3419 / 3428

页数：10

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