Synergic effect of palladium-based bimetallic catalysts for the hydrogenation of nitroaromatics

被引：21

作者：

Wan, BS ^{[1
]}

Liao, SJ ^{[1
]}

Xu, Y ^{[1
]}

Yu, DR ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1998年 / 63卷 / 02期

基金：

中国国家自然科学基金;

关键词：

synergic effect; bimetallic catalysts; hydrogenation;

D O I：

10.1007/BF02475418

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Bimetallic catalysts, PdCl2-MXn and PdCl2(PhCN)(2)-Mx(n) (MXn = FeCl3 Fe(acac)(3), Co(OAc)(2), CoCl2, Co(acac)(2), NiCl2, Ni(OAc)(2), RuCl3, Cu(OAc)(2), CuCl2), exhibit remarkable synergic effect which can obviously increase the activity of the monometallic Pd catalyst for the hydrogenation of nitroaromatics, whereas MXn alone is not catalytically active under the same reaction conditions.

引用

页码：397 / 401

页数：5

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