Convergent cyclopentannelation process

被引：22

作者：

Bee, C

Tius, MA

机构：

[1] Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA

[2] Canc Res Ctr Hawaii, Honolulu, HI 96813 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 10期

关键词：

D O I：

10.1021/ol034309+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A triply convergent synthesis of alpha-methylene cyclopentenones has been demonstrated in which an intermediate C,O-dianion is formed and trapped on carbon by electrophiles.

引用

页码：1681 / 1684

页数：4

共 20 条

[1] Nazarov-initiated diastereoselective cascade polycyclization of aryltrienones
Bender, JA
Arif, AM
West, FG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) : 7443 - 7444
[2] ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID, A VERSATILE REAGENT FOR DETERMINATION OF ENANTIOMERIC COMPOSITION OF ALCOHOLS AND AMINES
DALE, JA
DULL, DL
MOSHER, HS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (09) : 2543 - &
[3] NUCLEAR MAGNETIC-RESONANCE ENANTIOMER REAGENTS - CONFIGURATIONAL CORRELATIONS VIA NUCLEAR MAGNETIC-RESONANCE CHEMICAL-SHIFTS OF DIASTEREOMERIC MANDELATE, O-METHYLMANDELATE, AND ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETATE (MTPA) ESTERS
DALE, JA
MOSHER, HS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (02) : 512 - 519
[4] SULFONE REAGENTS IN ORGANIC-SYNTHESIS .5. ELECTRON-TRANSFER PROCESSES IN THE ALKYLATION OF ALPHA,BETA-UNSATURATED SULFONES BY ORGANOMETALLIC REAGENTS
EISCH, JJ
BEHROOZ, M
GALLE, JE
[J]. TETRAHEDRON LETTERS, 1984, 25 (43) : 4851 - 4854
[5] Habermas K.L., 1994, ORG REACTIONS, V45, P1
[6] Asymmetric cyclopentannelation: Camphor-derived auxiliary
Harrington, PE
Murai, T
Chu, C
Tius, MA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (34) : 10091 - 10100
[7] Hashmi ASK, 1998, TETRAHEDRON LETT, V39, P7491
[8] HOFF S, 1968, RECL TRAV CHIM PAY-B, V87, P916
[9] ENYNONES IN ORGANIC-SYNTHESIS .1. SPIROANNULATION BY TANDEM OXY-COPE REARRANGEMENT-ELECTROCYCLIC RING-CLOSURE
JACOBI, PA
ARMACOST, LM
KRAVITZ, JI
MARTINELLI, MJ
SELNICK, HG
[J]. TETRAHEDRON LETTERS, 1988, 29 (52) : 6865 - 6868
[10] Parallel synthesis and biocatalytic amplification of a cross-conjugated cyclopentenone library
Jang, WB
Hu, HP
Lieberman, MM
Morgan, JA
Stergiades, IA
Clark, DS
Tius, MA
[J]. JOURNAL OF COMBINATORIAL CHEMISTRY, 2001, 3 (04): : 346 - 353

← 1 2 →