The KSCN family: Structural properties and phase transitions of crystals with three-atomic linear anions

被引：27

作者：

Fuith, A

机构：

[1] Institute of Experimental Physics, University of Vienna, A-1090 Vienna

来源：

PHASE TRANSITIONS | 1997年 / 62卷 / 1-2期

关键词：

phase transitions; crystal structures; cyanates; thiocyanates; azides; bifluorides;

D O I：

10.1080/01411599708220061

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The article deals with ionic crystals of the type A(+)B(-) where the cations are alkali, NH4+ or Tl+ ions and the anions are the triatomic linear entities SCN-, OCN-, N-3(-) and HF2-. These crystals show a large variety of crystallographic phases which are based on the orientational degrees of freedom of the linear anions. The structure of the anions, the crystal structures, phase diagrams and phase transitions are reviewed.

引用

页码：1 / 93

页数：93

共 204 条

[1] VIBRATIONAL SPECTROSCOPY AT HIGH-PRESSURES .50. A RAMAN-SCATTERING STUDY OF KSCN, RBSCN, CSSCN, NH4SCN AT HIGH-PRESSURES [J].