Catalytic conversions in water.: Part 9.: High activity of the Pd/dpppr-s Bronsted acid system in the alternating copolymerization of ethene and carbon monoxide {dpppr-s = C3H6-1,3-[P(C6H4-m-SO3Na)2]2}

被引:69
作者
Verspui, G [1 ]
Papadogianakis, G [1 ]
Sheldon, RA [1 ]
机构
[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2826 BL Delft, Netherlands
关键词
D O I
10.1039/a707572c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The formation of alternating copolymers of ethene and carbon monoxide proceeds rapidly in the aqueous phase in the presence of a water-soluble palladium catalyst and a Bronsted acid; activities of >4 kg of polymer per g palladium per hour were observed.
引用
收藏
页码:401 / 402
页数:2
相关论文
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