Stability of gaseous fullerene chlorides

被引：3

作者：

Dorozhko, PA

Popov, AA

Korobov, MV

Tumanskii, BL

机构：

[1] Moscow State Univ, Dept Chem, Moscow, Russia

[2] Russian Acad Sci, Inst Organoelement Cpds, Moscow, Russia

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 287卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(98)00136-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Individual gaseous species of fullerene chlorides have been successfully generated in a molecular beam. Knudsen cell mass spectrometry has been used to detect C60C2n (n = 0...9), C70C2m (m = 0...7) in the vapour over the system C-60/C-70 (extract) with CrCl3 FeCl3 . 6H(2)O, FeCl3 (anhydrous) and CuCl2 (anhydrous) at temperatures from 520 to 720 K. Bond dissociation enthalpies for the fullerene chlorides have been estimated. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：154 / 161

页数：8

共 13 条

[1] PREPARATION AND C-13 NMR SPECTROSCOPIC CHARACTERIZATION OF C-60CL6 [J].