A facile approach to the synthesis of highly electroactive Pt nanoparticles on graphene as an anode catalyst for direct methanol fuel cells

被引:288
作者
Zhou, Yi-Ge [1 ]
Chen, Jing-Jing [1 ]
Wang, Feng-bin [1 ]
Sheng, Zhen-Huan [1 ]
Xia, Xing-Hua [1 ]
机构
[1] Nanjing Univ, Chem Sch Chem & Chem Engn, Key Lab Analyt Chem Life Sci, Nanjing 210093, Peoples R China
基金
中国国家自然科学基金;
关键词
GRAPHITE; CARBON; PERFORMANCE; NANOSHEETS; COMPOSITE; OXIDE;
D O I
10.1039/c0cc00394h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A one-step electrochemical approach to the synthesis of highly dispersed Pt nanoparticles on graphene has been proposed. The resultant Pt NPs@G nanocomposite shows higher electrocatalytic activity and long-term stability towards methanol electrooxidation than the Pt NPs@Vulcan.
引用
收藏
页码:5951 / 5953
页数:3
相关论文
共 24 条
[1]   Carbon-based electronics [J].
Avouris, Phaedon ;
Chen, Zhihong ;
Perebeinos, Vasili .
NATURE NANOTECHNOLOGY, 2007, 2 (10) :605-615
[2]   PMMA/graphite nanosheets composite and its conducting properties [J].
Chen, GH ;
Weng, WG ;
Wu, DJ ;
Wu, CL .
EUROPEAN POLYMER JOURNAL, 2003, 39 (12) :2329-2335
[3]   Nanostructured Coral-like Carbon as Pt Support for Fuel Cells [J].
Chen, Wei-Fu ;
Wang, Jing-Ping ;
Hsu, Chun-Han ;
Jhan, Jing-Yi ;
Teng, Hsisheng ;
Kuo, Ping-Lin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (15) :6976-6982
[4]   Raman spectroscopy of graphene and graphite: Disorder, electron-phonon coupling, doping and nonadiabatic effects [J].
Ferrari, Andrea C. .
SOLID STATE COMMUNICATIONS, 2007, 143 (1-2) :47-57
[5]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[6]   The use of graphite oxide to produce mesoporous carbon supporting Pt, Ru, or Pd nanoparticles [J].
Gotoh, Kazuma ;
Kawabata, Koji ;
Fujii, Eiji ;
Morishige, Kunimitsu ;
Kinumoto, Taro ;
Miyazaki, Yuki ;
Ishida, Hiroyuki .
CARBON, 2009, 47 (08) :2120-2124
[7]   A Green Approach to the Synthesis of Graphene Nanosheets [J].
Guo, Hui-Lin ;
Wang, Xian-Fei ;
Qian, Qing-Yun ;
Wang, Feng-Bin ;
Xia, Xing-Hua .
ACS NANO, 2009, 3 (09) :2653-2659
[8]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[9]   High-performance direct methanol fuel cell electrodes using solid-phase-synthesized carbon nanocoils [J].
Hyeon, T ;
Han, S ;
Sung, YE ;
Park, KW ;
Kim, YW .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (36) :4352-4356
[10]  
KOVTYUKHOVA NI, 1999, CHEM MATER, V11