trans-bis[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bis[4-(trimethylsilyl)buta-1,3-diynyl]ruthenium(II) and trans-bis[1,2-bis(diphenylphosphino)ethane-κ2P,P′]bis(buta-1,3-diynyl)ruthenium(II)

被引：6

作者：

Anderson, JN

Brookes, NJ

Coe, BJ

Coles, SJ

Light, ME

Hursthouse, MB

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[2] Univ Southampton, Dept Chem, EPSRC Xray Crystallog Serv, Southampton SO17 1BJ, Hants, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷

关键词：

D O I：

10.1107/S0108270103007716

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of the title compounds, [Ru(C7H9Si)(2)(C26H24P2)(2)] and [Ru(C4H)(2)(C26H24P2)(2)], are described. The metal centre in both complexes has an octahedral coordination geometry, with mutually trans buta-1,3-diynyl ligands forming pseudo-linear ruthenium-centred polyyne chains.

引用

收藏

页码：M215 / M217

页数：3

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