Thermally stable fatigue resistant near infrared active photochromic compounds, exemplified by 6-amino-7-cyano-3-(dicyclopropylmethylene)-4-(2,5-dimethyl-3-furyl)-benzofuran-2(3H)-one

被引:17
作者
Heller, HG [1 ]
Hughes, DS [1 ]
Hursthouse, MB [1 ]
Rowles, NG [1 ]
机构
[1] Cardiff Univ, Dept Chem, Cardiff CF1 3TP, S Glam, Wales
关键词
D O I
10.1039/b003496g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title pale yellow photochromic compound 11b in toluene, on irradiation at 366 nm, cyclises to the thermally stable infrared active blue-green photochrome, 8-amino-7-cyano-4,4-dicyclopropyl-3a,4-dihydro-6-hydroxy-2,3a-dimethylnaphtho[2,1-b]furan-5,6-carbolactone, 12b which has a lambda(max) value of 720 nm for its broad long wavelength absorption band.
引用
收藏
页码:1397 / 1398
页数:2
相关论文
共 3 条
[1]   A NEW CLASS OF PHOTOCHROMIC COMPOUNDS EXEMPLIFIED BY E-5-DICYANOMETHYLENE-4-(DIALKYL AND DICYCLOALKYL)METHYLENE[1-(2,5-METHYL-3-FURYL) AND (2-METHYL-5-PHENYL-3-THIENYL)ETHYLIDENE]TETRAHYDROFURAN-2-ONES [J].
HELLER, HG ;
HUGHES, DS ;
HURSTHOUSE, MB ;
KOH, KVS .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (23) :2713-2714
[2]   NOVEL SYNTHESES OF NAPHTHOQUINONE METHIDE NEAR-INFRARED DYES [J].
KUBO, Y ;
MORI, F ;
KOMATSU, K ;
YOSHIDA, K .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (08) :2439-2442
[3]  
SUN ZY, 1995, TETRAHEDRON LETT, V36, P3453