A nanotubular 3D coordination polymer based on a 3D-4f heterometallic assembly

被引：513

作者：

Zhao, B ^{[1
]}

Cheng, P ^{[1
]}

Dai, Y ^{[1
]}

Cheng, C ^{[1
]}

Liao-Zheng, D ^{[1
]}

Yan, SP ^{[1
]}

Jiang, ZH ^{[1
]}

Wang, GL ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 08期

关键词：

D O I：

10.1002/anie.200390248

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Large pores comprising 48-membered rings characterize the isostructural lanthanide-transition-metal coordination polymers [{[Ln(dipic)3Mn1.5(H2O)3]· nH2O}∞], H2dipic = pyridine-2,6-dicarboxylic acid; Ln = Pr, n = 2 (shown here); Ln = Gd, n = 3.5; Ln = Er, n = 3. Many water molecules are trapped in the nanotubular structure, and the framework remains intact on removal of the uncoordinated water molecules.

引用

页码：934 / +

页数：4

共 48 条

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