Programmed formation of nanogels via a radical crossover reaction of complementarily reactive diblock copolymers

被引:22
作者
Amamoto, Yoshifumi
Higaki, Yuji
Matsuda, Yasuhiro
Otsuka, Hideyuki
Takahara, Atsushi
机构
[1] Kyushu Univ, Grad Sch Engn, Nishi Ku, Fukuoka 819, Japan
[2] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, Fukuoka 819, Japan
关键词
D O I
10.1246/cl.2007.774
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By heating two types of diblock copolymers with complementarily reactive alkoxyamine units in the side chains, nanogels were formed as a result of a radical crossover reaction of the alkoxyamine units. The transformation from the diblock copolymers to nanogels and their absolute molecular weight were obviously dependent on reaction concentrations and the mixing ratio of two types of diblock copolymers.
引用
收藏
页码:774 / 775
页数:2
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