Prediction of water solubility in nylon melts based on Flory-Huggins theory

被引：13

作者：

Schaffer, MA

Mcauley, KB ^{[1
]}

Cunningham, MF

Marchildon, EK

机构：

[1] Queens Univ, Dept Chem Engn, Kingston, ON K7L 3N6, Canada

[2] DuPont Canada Inc, Res & Business Dev Ctr, Kingston, ON K7L 5A5, Canada

来源：

POLYMER ENGINEERING AND SCIENCE | 2003年 / 43卷 / 03期

关键词：

D O I：

10.1002/pen.10052

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The solubility of water in molten aliphatic polyamides (nylons) of high degrees of polymerization at conditions of subatmospheric water partial pressure and high temperature (225 to 300degreesC) has been modeled. A simple, serni-empirical model based on Flory-Huggins theory was fit to the available literature data for nylons 6, 66, 610 and 11 and to new experimental data for nylon 612. The model contains only two fitted parameters, and is able to adequately describe the available data for the effects of temperature and nylon type on the water concentration in the melt at various water partial pressures.

引用

页码：639 / 646

页数：8

共 32 条

[1] Simulation of hydrolytic polymerization of nylon-6 in industrial reactors: Part I. Mono-acid-stabilized systems in VK tube reactors [J].