Charge assisted chiral hybrid H-bonded molecular networks

被引:38
作者
Ferlay, S [1 ]
Holakovsky, R [1 ]
Hosseini, MW [1 ]
Planeix, JM [1 ]
Kyritsakas, N [1 ]
机构
[1] Univ Strasbourg, Chim Coordinat Organ Lab, Serv Commun Rayons 10, F-67000 Strasbourg, France
关键词
D O I
10.1039/b301467n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The co-crystallisation of [Fe(CN)(5)NO](2-) and cyclic achiral 1(2+) and chiral 2(2+) or 3(2+) bisamidinium tectons leads in the crystalline phase to the formation of 1-D H-bonded achiral and chiral molecular networks respectively. In all cases, the network is formed by mutual bridging of the anionic and cationic units through a chelate mode of H-bonding.
引用
收藏
页码:1224 / 1225
页数:2
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