Anionic vinyl polymerization -: 50 years after Michael!Szwarc

被引：204

作者：

Baskaran, Durairaj

Mueller, Axel H. E.

机构：

[1] Univ Bayreuth, D-95440 Bayreuth, Germany

[2] Natl Chem Lab, Div Polymer Sci & Engn, Pune 411008, Maharashtra, India

来源：

PROGRESS IN POLYMER SCIENCE | 2007年 / 32卷 / 02期

关键词：

anionic polymerization; carbanions; mechanisms; ion-pairs; kinetics; history;

D O I：

10.1016/j.progpolymsci.2007.01.003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We present a review on the present status of anionic polymerization of important non-polar and polar vinyl monomers. After presenting the historical background-the "pre-Szwarc" era-we discuss the mechanisms of this polymerization, in particular several types of carbanions, their ion-pairs and their aggregates occurring in the initiation and propagation of non-polar and polar monomers, including recent developments. Finally, we discuss some important scientific and industrial applications of anionic polymerization. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：173 / 219

页数：47

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