Effect of heating rate on nanoparticle formation of poly(N-isopropylacrylamide)-poly(ethylene glycol) block copolymer microgels

被引:46
作者
Zhu, PW [1 ]
Napper, DH [1 ]
机构
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
关键词
D O I
10.1021/la000489+
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The colloidal behavior of poly(N-isopropylacrylamide) and poly(ethylene oxide) (PNIPAM-b-PEO) block copolymers and their corresponding microgels in aqueous solutions were studied. The microgels were synthesized using a redox system consisting of ceric ion (Ce) and PEO. The nanoparticles formation of the microgels were controlled by changing the heating rates. Smaller particle dimension with a narrower size microgels were obtained by the fast heating process.
引用
收藏
页码:8543 / 8545
页数:3
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