Dineodymium dihydrogen α-hexamolybdoplatinate(IV) tetradecahydrate, Nd2[H2α-PtMo6O24]•14H2O

被引：17

作者：

Lee, U ^{[1
]}

Joo, HC ^{[1
]}

机构：

[1] Pukyong Natl Univ, Dept Chem, Pusan 608737, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷

关键词：

D O I：

10.1107/S0108270100009689

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The least protonated hexamolybdoplatinate(IV) polyanion, [H(2)alpha-PtMo6O24](6-), is isolated by using Nd3+ as a counter-cation. Two O atoms of the central PtO6 octahedron are protonated. The Mo-Mo distances are 3.244 (2), 3.295 (2) and 3.393 (1) Angstrom, and the Pt-Mo distances are 3.251 (1), 3.332 (2) and 3.338 (1) Angstrom. The anion has the Pt atom on an inversion centre and has close to (3) over bar m symmetry, with Pt-O bond lengths in the range 2.002 (8)-2.015 (8) Angstrom and Mo-O bond lengths in the ranges 1.689 (9)-1.747 (8), 1.890 (8)- 2.037 (8) and 2.109 (8)-2.384 (8) Angstrom.

引用

页码：E311 / E312

页数：2

共 6 条

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[6]

*STOE CIE, 1996, STADI4 XRED

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