Effect of dc electric field on conductivity and giant permittivity of KxTiyNi1-x-yO
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作者:
Jana, Pradip Kumar
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机构:Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India
Jana, Pradip Kumar
Sarkar, Sudipta
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机构:Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India
Sarkar, Sudipta
Chaudhuri, B. K.
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机构:Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India
Chaudhuri, B. K.
Sakata, H.
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Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, IndiaIndian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India
Sakata, H.
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机构:
[1] Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India
[2] Tokai Univ, Dept Appl Chem, Kanagawa 1117, Japan
Activation energies (E-a) for electrode and grain boundary (GB) conduction are found to be greater than that of the bulk conduction. This implies that both electrode and GB act as two insulating barriers affecting conductivity and dielectric relaxations in KxTiyNi1-x-yO. Decrease in E-a for electrode conduction above T>295 K leads to relatively greater loss due to the dc-charge transportation between electrodes and dielectric. The Cole-Cole equation has been modified to explain epsilon(') over a wide range of frequency (10-10(7) Hz). Impedance spectroscopic study has also been employed to distinguish electrode relaxation from GB relaxation. (c) 2007 American Institute of Physics.